1. players is in game, not workspace
2. that would only work in a server script if the player you wanted to remove the head from was called Player, otherwise use a localscript and get the player through LocalPlayer
3. the head is a part of the character, not the player
4. use Destroy() instead of remove()
5. you may have to wait until the character is loaded before deleting the head
so in a localscript it would be something like this
game.Players.LocalPlayer.Character:WaitForChild("Head"):Destroy()
or if you had the name, you could do it like this in a server script
game.Players["playername"].Character:WaitForChild("Head"):Destroy()
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